Influence laws of air gap structure manipulation of covalent organic frameworks on dielectric properties and exciton effects for photopolymerization
Hongjie Yang, Zhen Lu, Xiangyu Yin, Shengjin Wu, Linxi Hou
Abstract
to facilitate exciton dissociation. Meanwhile, taking "water-/oxygen-fueled" photo-induced electron transfer reversible addition-fragmentation chain transfer (PET-RAFT) polymerization as a demonstration platform, it can be seen that COFs with a small "air gap" structure have relatively superior photocatalytic activity. This provides important implications for the evolution of efficient photocatalysts.
Topics & Concepts
PhotopolymerExcitonDielectricMaterials scienceCovalent bondChemical physicsNanotechnologyOptoelectronicsChemistryPolymerizationPhysicsPolymerCondensed matter physicsOrganic chemistryComposite materialCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications