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Effect of Different Gel Electrolytes on Conjugated Polymer - Graphene Quantum Dots Based Electrode for Solid State Hybrid Supercapacitors

Vandana Molahalli, H. Vijeth, S. P. Ashokkumar, H. Devendrappa

2020Polymer-Plastics Technology and Materials16 citationsDOI

Abstract

A solid-state supercapacitor was designed based on conjugated polymer – quantum dots composite synthesized by the in-situ chemical method. The polypyrrole-graphene quantum dots composite (PGC) was used to preparation of flexible supercapacitor electrode with various PVA/KOH, PVA/H3PO4, PVA/H2SO4, PVA/KCl gel electrolytes. It is observed that PPY-GQDs exhibited a maximum specific capacitance of 730 F/g for PVA/H3PO4 gel electrolyte. The Nyquist plots of supercapacitors have been measured. The optimization of concentrations of electrically conducting substances in polymer gel enhanced the electrochemical properties of the supercapacitor. This shows the latest accomplishment in this field and provides insight advancement in supercapacitor.

Topics & Concepts

SupercapacitorMaterials scienceGrapheneElectrolytePolypyrroleCapacitanceElectrodeConductive polymerPolymerQuantum dotConjugated systemNanotechnologyComposite numberNyquist plotChemical engineeringElectrochemistryComposite materialChemistryPolymerizationDielectric spectroscopyPhysical chemistryEngineeringSupercapacitor Materials and FabricationConducting polymers and applicationsElectrochemical sensors and biosensors