π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons
Marta Martínez‐Abadía, Karol Strutyński, Belén Lerma‐Berlanga, Craig T. Stoppiello, Andrei N. Khlobystov, Carlos Martí‐Gastaldo, Akinori Saeki, Manuel Melle‐Franco, Aurelio Mateo‐Alonso
Abstract
Abstract Three‐dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic ( D 3 d ) nodes. Such 3D COFs are six‐fold interpenetrated as the result of interframework π‐stacking, which enable charge transport properties that are not expected for 3D COFs.
Topics & Concepts
StackingCovalent bondCovalent organic frameworkAromaticityChemistryTopology (electrical circuits)Materials scienceOrganic chemistryMoleculeEngineeringElectrical engineeringCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsGraphene research and applications