Sulfonyl radical triggered selective iodosulfonylation and bicyclization of 1,6-dienes
Shi-Ping Wu, Dongkai Wang, Qing‐Qing Kang, Guo‐Ping Ge, Hongxing Zheng, Meiling Zhu, Ting Li, Jun‐Qi Zhang, Wen‐Ting Wei
Abstract
A novel sulfonyl radical triggered selective iodosulfonylation and bicyclization of 1,6-dienes has been described for the first time. High selectivity and efficiency, mild reaction conditions, excellent functional group compatibility, and broad substrate scope are the attractive features of this synthetic protocol, which provides a unique platform for precise radical cyclization.
Topics & Concepts
SulfonylChemistrySelectivityFunctional groupCombinatorial chemistryCompatibility (geochemistry)Substrate (aquarium)RadicalOrganic chemistryCatalysisMaterials sciencePolymerComposite materialGeologyOceanographyAlkylSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsCatalytic C–H Functionalization Methods