Effect of ball-milling time on chemical property of coconut shell powder
Ismail Ismail, Arliyani, Syarifah Fathmiyah, Mursal Mursal, Zulkarnain Jalil, H. P. S. Abdul Khalil
Abstract
Abstract Coconut is one of the abundant agricultural products in Indonesia. Coconut shell is one of the wastes from coconut products that can be used as biocomposite material. The purpose of this study was to find out the effect of ball milling time on the chemical properties of coconut shell powder. X-ray diffraction (XRD) and X-ray fluorescent (XRF) have been used in this study. Coconut shell powder 200 mesh was milled using mechanical ball milling for various milling times (20, 30, and 40 hours) at 350 rpm constant speed. The results of our study using XRD showed that the coconut shell powder contains SiO 2 , C, Fe 2 O 3 , CaO, K 2 O, and Al 2 O 3 . The intensity of the diffraction pattern from our sample increased when the ball-milling time was increased. This implies that the crystallinity of the sample was influenced by the ball-milling time. By using XRF, it was found that the coconut shell powder contains 13.6% of Fe 2 O 3 , 25.7% of CaO, 46.1% of K 2 O, 2.8% of CuO, and 8.2% of P 2 O 5 . The percentage composition of Fe 2 O 3 increased from 13.6% for 0 hours milling time to 30.2% after the sample was milled for 20 hours. The percentage composition of Fe 2 O 3 rose to 32.2% for the milling time of 40 hours. However, the percentage compositions of CaO and K 2 O decrease as the milling time is increased. The percentage composition of P 2 O 5 is independent of milling time. Our results show that the chemical properties of coconut shell powder are influenced by the ball-milling time or particle size of coconut shell powder.