Tuning the structure and the properties of dithiafulvene metalla-assembled tweezers
Maksym Dekhtiarenko, Serhii Krykun, Vincent Carré, Frédéric Aubriet, David Canevet, Magali Allain, Zoia Voïtenko, Marc Sallé, Sébastien Goeb
Abstract
An electroactive M<sub>2</sub>L<sub>2</sub> metalla-macrocycle constructed through coordination driven self-assembly dimerizes upon oxidation and binds an electro-deficient substrate with a high association constant.
Topics & Concepts
TweezersSubstrate (aquarium)CrystallographyNanotechnologyMaterials scienceChemistryStereochemistryPhysicsCombinatorial chemistryPhysical chemistryOceanographyGeologySupramolecular Chemistry and ComplexesMolecular Sensors and Ion DetectionCrystallography and molecular interactions