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PET recycling under mild conditions <i>via</i> substituent-modulated intramolecular hydrolysis

Shengbo Zhang, Yingying Xue, Yanfen Wu, Yu‐Xiao Zhang, Ting Tan, Zhiqiang Niu

2023Chemical Science67 citationsDOIOpen Access PDF

Abstract

A set of substituted binuclear zinc catalysts are employed to investigate the structure–activity relationship in PET hydrolysis, which leads to the identification of a new catalyst with four times more activity than the methyl-substituted one.

Topics & Concepts

Intramolecular forceSubstituentHydrolysisCatalysisChemistryZincMedicinal chemistryStereochemistryOrganic chemistryRecycling and Waste Management TechniquesMicroplastics and Plastic PollutionChemistry and Chemical Engineering