The Nonphysiological Reductant Sodium Dithionite and [FeFe] Hydrogenase: Influence on the Enzyme Mechanism
Maria Alessandra Martini, Olaf Rüdiger, Nina Breuer, Birgit Nöring, Serena DeBeer, Patricia Rodríguez‐Maciá, James A. Birrell
Abstract
. The broader potential implications of using a nonphysiological reductant in spectroscopic and mechanistic studies of enzymes are highlighted.
Topics & Concepts
ChemistrySodium dithioniteDithioniteRedoxHydrogenaseCatalysisPhotochemistryInorganic chemistryProtonationSulfiteActive siteEnzymeOrganic chemistryIonMetalloenzymes and iron-sulfur proteinsElectrocatalysts for Energy ConversionAdvanced battery technologies research