Luminescence of ESIPT-capable zinc(<scp>ii</scp>) complexes with a 1-hydroxy-1<i>H</i>-imidazole-based ligand: exploring the impact of substitution in the proton-donating moiety
Nikita A. Shekhovtsov, Елена Б. Николаенкова, Sofya N. Vorobyova, Victor F. Plyusnin, Katerina A. Vinogradova, Taisiya S. Sukhikh, А. Ya. Tikhonov, Mark B. Bushuev
Abstract
-imidazoles and their zinc(II) complexes allowed us to reveal the influence of expanding π-conjugation in the proton-donating and proton-accepting moieties on the stabilization/destabilization of the T-form and on the position of the emission band.
Topics & Concepts
MoietyLuminescenceImidazoleLigand (biochemistry)ChemistryZincSubstitution (logic)ProtonPhotochemistryMedicinal chemistryStereochemistryCombinatorial chemistryReceptorOrganic chemistryMaterials scienceBiochemistryOptoelectronicsPhysicsProgramming languageComputer scienceQuantum mechanicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal complexes synthesis and properties