Photocatalytic, site-selective oxidations of carbohydrates
Daniel J. Gorelik, Victoria Dimakos, Timur Adrianov, Mark S. Taylor
Abstract
-1,2-diols. Site-selectivity reflects the relative rates of hydrogen atom transfer from the carbohydrate C-H bonds, and can be enhanced using a phosphate hydrogen-bonding or boronic acid catalyst.
Topics & Concepts
ChemistryCatalysisPhotocatalysisQuinuclidineSelectivityHydrogen bondPhotochemistryHydrogen atomBoronic acidOrganic chemistryCombinatorial chemistryMoleculeAlkylRadical Photochemical ReactionsCarbohydrate Chemistry and SynthesisFluorine in Organic Chemistry