Litcius/Paper detail

Electro-Synthesized Bismuth Oxide Nanomaterials on Flexible Substrate Electrode for Supercapacitor Application

Vandana Suryavanshi, Rushikesh G. Bobade, B. J. Lokhande, R.C. Ambare

2023ES Energy & Environments27 citationsDOIOpen Access PDF

Abstract

The present article report on synthesis and electrochemical supercapacitor application of bismuth oxide (Bi2O3) deposited on stainless still (SS) substrate using a low cost and simplest electrodeposition methods.The structural analyses of the produced samples reveal polycrystalline with a tetragonal crystal structure.It has been obtained to synthesized linked adherence and compact surface morphology and TEM reveals nanoplates-like surface appearance.Electrochemical supercapacitive concert of Bi2O3 thin film electrode has been performed through cyclic voltammetry (CV), charge-discharge (CD), and impedance spectroscopy (EIS) in aqueous 1M KOH electrolyte.The Bi2O3 thin film electrode obtained the highest specific capacitance (SC) of 1227.5 F/g at 2 mV/Sec scan rate in 1M KOH.Obtained maximum value of specific energy (SE) and specific power (SP) was 191.14 Wh/Kg and 4.8 kW/kg at 18 mA/cm 2 in 1M KOH electrolyte respectively.93.29 % capacitance retention after 3500 CV cycles.

Topics & Concepts

SupercapacitorCyclic voltammetryMaterials scienceHorizontal scan rateDielectric spectroscopyBismuthElectrodeElectrolyteCapacitanceElectrochemistryTetragonal crystal systemChemical engineeringSubstrate (aquarium)Thin filmOxideCrystalliteNanomaterialsAnalytical Chemistry (journal)NanotechnologyChemistryCrystal structureMetallurgyChromatographyOrganic chemistryOceanographyGeologyEngineeringPhysical chemistrySupercapacitor Materials and FabricationConducting polymers and applicationsAdvanced Sensor and Energy Harvesting Materials