Propylene homopolymerization and copolymerization with ethylene by acenaphthene-based α-diimine nickel complexes to access EPR-like elastomers
Beibei Wang, Heng Liu, Chunyu Zhang, Tao Tang, Xuequan Zhang
Abstract
A series of acenaphthene-based α -diimine nickel complexes were synthesized and subsequently used for accessing branched EPR-like elastomers with different compositions and chain structures.
Topics & Concepts
AcenaphtheneDiimineCopolymerNickelElectron paramagnetic resonanceElastomerEthylene propylene rubberPolymer chemistryEthyleneChemistryPhotochemistryMaterials sciencePolymerOrganic chemistryCatalysisNuclear magnetic resonanceAnthracenePhysicsOrganometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysisSynthetic Organic Chemistry Methods