The Use of the Thiol-Ene Addition Click Reaction in the Chemistry of Organosilicon Compounds: An Alternative or a Supplement to the Classical Hydrosilylation?
Ilya Krizhanovskiy, Maxim N. Temnikov, Yuriy N. Kononevich, Anton A. Anisimov, Fedor V. Drozdov, Aziz M. Muzafarov
Abstract
This review presents the main achievements in the use of the thiol-ene reaction in the chemistry of silicones. Works are considered, starting from monomers and ending with materials.The main advantages and disadvantages of this reaction are demonstrated using various examples. A critical analysis of the use of this reaction is made in comparison with the hydrosilylation reaction.
Topics & Concepts
OrganosiliconHydrosilylationEne reactionClick chemistryOrganic chemistryChemistryMonomerThiolPolymer sciencePolymer chemistryPolymerCatalysisSilicone and Siloxane ChemistryOrganoboron and organosilicon chemistrySynthesis and characterization of novel inorganic/organometallic compounds