Iron- and copper-based bifunctional catalysts for the base- and solvent-free C–N coupling of amines and aryl/benzyl chlorides under aerobic conditions
Charu Sharma, Avinash K. Srivastava, Deepak Sharma, Raj K. Joshi
Abstract
The chalcogenised ironcarbonyl clusters Fe 3 Se 2 (CO) 9 and Cu(OAc) 2 were found to be outstanding bimetallic catalyst for the Buchwald type C–N cross coupling reaction of amine and aryl chloride.
Topics & Concepts
ChemistryBimetallic stripArylCatalysisBifunctionalCopperAmine gas treatingBase (topology)ChlorideSolventMedicinal chemistryPolymer chemistryIron(III) chlorideOrganic chemistryAlkylMathematicsMathematical analysisCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsAsymmetric Hydrogenation and Catalysis