Copper catalyzed borocarbonylation of benzylidenecyclopropanes through selective proximal C–C bond cleavage: synthesis of γ-boryl-γ,δ-unsaturated carbonyl compounds
Li‐Miao Yang, Hui-Hui Zeng, Xin‐Lian Liu, Ai‐Jun Ma, Jin‐Bao Peng
Abstract
-isomers as the products. This efficient methodology involves the cleavage of a C-C bond and the formation of a C-C bond as well as a C-B bond, and provides a new method for the proximal C-C bond difunctionalization of BCPs.
Topics & Concepts
ChemistryBond cleavageStereoselectivityCleavage (geology)CatalysisCopperOrganic synthesisMedicinal chemistryStereochemistryOrganic chemistryMaterials scienceComposite materialFracture (geology)Cyclopropane Reaction MechanismsCatalytic C–H Functionalization MethodsOrganoboron and organosilicon chemistry