A study of cation-dependent inverse hydrogen bonds and magnetic exchange-couplings in lanthanacarborane complexes
Peng‐Bo Jin, Qian‐Cheng Luo, Yuan‐Qi Zhai, Yidian Wang, Yan Ma, Lei Tian, Xinliang Zhang, Chao Ke, Xu‐Feng Zhang, Yi Lv, Yan‐Zhen Zheng
Abstract
bonding energy is reduced to 14 kJ/mol, and the dimerization process is no longer reversible. The exchange-biasing effect is also disappeared. We believe such a finding extends our knowledge of IHBs.
Topics & Concepts
ChemistryHydrogen bondDysprosiumCrystallographyCoupling (piping)Activation energyCoupling constantBiasingComputational chemistryPhysical chemistryInorganic chemistryMoleculeMaterials sciencePhysicsOrganic chemistryVoltageQuantum mechanicsMetallurgyParticle physicsMagnetism in coordination complexesAdvanced NMR Techniques and ApplicationsLanthanide and Transition Metal Complexes