Activation of H–H, HO–H, C(sp<sup>2</sup>)–H, C(sp<sup>3</sup>)–H, and RO–H Bonds by Transition-Metal Frustrated Lewis Pairs Based on M/N (M = Rh, Ir) Couples
María Carmona, Roberto Pérez, Joaquina Ferrer, Ricardo Rodrı́guez, Vincenzo Passarelli, Fernando J. Lahoz, Pilar García‐Orduña, Daniel Carmona
Abstract
crystallize both as enantiopure conglomerates and as racemates. Reaction mechanisms are proposed based on stoichiometric reactions, nuclear magnetic resonance studies, and X-ray crystallography as well as density functional theory calculations.
Topics & Concepts
ChemistryProtonationDehydrogenationMetalLigand (biochemistry)Medicinal chemistryCrystal structureCrystallographyMethanolHydrogen bondYield (engineering)Transition metalAqueous solutionIntramolecular forceStereochemistryMoleculeCatalysisIonOrganic chemistryMaterials scienceMetallurgyBiochemistryReceptorOrganoboron and organosilicon chemistryCoordination Chemistry and OrganometallicsOrganometallic Complex Synthesis and Catalysis