Antisymmetric Spin Exchange in a μ-1,2-Peroxodicopper(II) Complex with an Orthogonal Cu–O–O–Cu Arrangement and <i>S</i> = 1 Spin Ground State Characterized by THz-EPR
Thomas Lohmiller, Can-Jerome Spyra, Sebastian Dechert, Serhiy Demeshko, Eckhard Bill, Alexander Schnegg, Franc Meyer
Abstract
activation at type III dicopper sites and a potential role of antisymmetric exchange in the concomitant intersystem crossing are proposed.
Topics & Concepts
Electron paramagnetic resonanceGround stateChemistryCrystallographyAdductAntisymmetric relationSinglet stateRaman spectroscopySquidCondensed matter physicsNuclear magnetic resonancePhysicsAtomic physicsExcited stateOrganic chemistryMathematical physicsEcologyBiologyOpticsMagnetism in coordination complexesMetal-Catalyzed Oxygenation MechanismsMetal complexes synthesis and properties