Pyrolysis of polystyrene waste for recovery of combustible hydrocarbons using copper oxide as catalyst
Jan Nisar, Ghulam Ali, Afzal Shah, Muhammad Naeem Ashiq, Zahoor H. Farooqi, Ahsan Sharif, Ejaz Ahmed, Munawar Iqbal, Syed Tufail Hussain Sherazi, Muhammad Raza Shah
Abstract
The present work is focused on pyrolysis of polystyrene waste for production of combustible hydrocarbons. The experiments were performed in an indigenously made furnace in the presence of a laboratory synthesised copper oxide. The pyrolysis products were collected and characterised. The Fourier transform infrared spectra showed that the liquid fraction contains C–H, C–O, C–C, C=C and O–H bonds, which correspond to various aliphatic and aromatic compounds. Gas chromatography–mass spectrometry traced compounds ranging from C 1 to C 4 in the gaseous fraction, whereas in the liquid fraction 15 components ranging from C 3 to C 24 were detected. From the results it has been concluded that CuO as a catalyst not only increased the liquid yield but also reduced the degradation temperature to great extent. Fuel properties of the pyrolysis oil were determined and compared with standard values of commercial fuel oil. The comparison suggested potential application of pyrolysis oil for domestic and commercial use.