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A <scp>CuO</scp>/<scp>TiO<sub>2</sub></scp> Heterojunction Based <scp>CO</scp> Sensor with High Response and Selectivity

Wei Wei, Huanhuan Zhang, Tiyue Tao, Xiaohong Xia, Yuwen Bao, M. A. Lourenço, K.P. Homewood, Zhongbing Huang, Yun Gao

2022Energy & environment materials48 citationsDOIOpen Access PDF

Abstract

The use of heterojunctions is a promising solution to the problem of cross‐sensitivity in gas sensors. In this work, a carbon monoxide sensor based on the CuO/TiO 2 heterojunction was designed and fabricated. Due to the good adsorption properties of CuO materials to CO, and the heterojunction interface charge transfer, the CuO/TiO 2 thin film sensor exhibits high sensitivity to CO at room temperature. The response is as high as 10.8–200 ppm CO, about 10 times its response to H 2 . Interference from H 2 is greatly reduced by optimizing the structure of the CuO/TiO 2 heterojunction. This reliable detection of carbon monoxide with excellent discrimination against H 2 is of great significance for the development of CO gas sensors.

Topics & Concepts

HeterojunctionCarbon monoxideMaterials scienceSensitivity (control systems)AdsorptionResponse timeSelectivityChemical engineeringNanotechnologyOptoelectronicsCatalysisChemistryElectronic engineeringComputer sciencePhysical chemistryOrganic chemistryComputer graphics (images)EngineeringGas Sensing Nanomaterials and SensorsZnO doping and propertiesAnalytical Chemistry and Sensors