Inverse and highly selective separation of CO<sub>2</sub>/C<sub>2</sub>H<sub>2</sub>on a thulium–organic framework
De‐Yun Ma, Zhi Li, Jiaxing Zhu, Yiping Zhou, Lilin Chen, Xufeng Mai, Meilin Liufu, Yinbing Wu, Yingwei Li
Abstract
A new Tm-based complex<bold>1</bold>is synthesized and activated at different temperatures to obtain two porous MOFs (<bold>1a</bold>and<bold>1a′</bold>) with different pore sizes and pore surfaces, in which<bold>1a</bold>shows an excellent capability to selectively capture CO<sub>2</sub>from CO<sub>2</sub>/C<sub>2</sub>H<sub>2</sub>.
Topics & Concepts
ThuliumMaterials scienceInversePorous mediumPorosityAnalytical Chemistry (journal)Physical chemistryChemistryDopingOptoelectronicsChromatographyMathematicsComposite materialGeometryMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsCarbon dioxide utilization in catalysis