On the limit of proton-coupled electronic doping in a Ti(<scp>iv</scp>)-containing MOF
Jenna L. Mancuso, Kevin Fabrizio, Carl K. Brozek, Christopher H. Hendon
Abstract
potential. Generally, we offer the design principle that inorganic anions in MOF nodes can host adatomic protons, which may stabilize meta-stable low valent transition metals. This approach highlights the unique chemistry afforded by MOFs built from inorganic clusters, and provides one avenue to developing novel catalytic scaffolds for hydrogen evolution and transfer hydrogenation.
Topics & Concepts
ProtonDopingChemistryElectronCatalysisDetection limitTransition metalHydrogenMetal-organic frameworkChemical physicsPhysical chemistryPhysicsCondensed matter physicsOrganic chemistryNuclear physicsChromatographyAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsMachine Learning in Materials ScienceAdvanced Photocatalysis Techniques