Visible-light photocatalysis promoted by solid- and liquid-phase immobilized transition metal complexes in organic synthesis
Alexei A. Yakushev, Anton S. Abel, Alexei D. Averin, I. P. Beletskaya, Andrei V. Cheprakov, Ilia S. Ziankou, Laurent Bonneviot, Alla Bessmertnykh‐Lemeune
Abstract
This review summarizes synthetic approaches to reusable photocatalytic systems based on visible light-active transition metal complexes with chelating ligands containing pyridyl residues such as 2,2′-bipyridines, 1,10-phenanthrolines, 2,2′:6′,2′′-terpyridines and related ligands. The use of these materials in organic synthesis is then discussed focusing on 1) most active systems exhibiting a synergy effect between photophysical properties of immobilized complexes and photoactive solid supports and 2) reusability of the developed catalytic system.
Topics & Concepts
ChemistryReusabilityPhotocatalysisTransition metalCatalysisVisible spectrumChelationCombinatorial chemistryOrganic synthesisPhotochemistryMetalNanotechnologyInorganic chemistryOrganic chemistryPhysicsComputer scienceProgramming languageSoftwareMaterials scienceOptoelectronicsRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques