Dramatic Enhancement of Rare-Earth Metal–Organic Framework Stability Via Metal Cluster Fluorination
Matthew S. Christian, Keith J. Fritzsching, Jacob Harvey, Dorina F. Sava Gallis, Tina M. Nenoff, Jessica Rimsza
Abstract
). Therefore, for the first time the presence of fluorine in the metal clusters was found to significantly stabilize RE-MOFs without changing their acid-gas adsorption properties.
Topics & Concepts
AdsorptionFluorineChemistryMetalMagic angle spinningMetal-organic frameworkBinding energyCluster (spacecraft)Fluorine-19 NMRDensity functional theoryInorganic chemistryPhysical chemistryComputational chemistryNuclear magnetic resonance spectroscopyOrganic chemistryProgramming languagePhysicsComputer scienceNuclear physicsMetal-Organic Frameworks: Synthesis and ApplicationsInorganic Fluorides and Related CompoundsMagnetism in coordination complexes