Litcius/Paper detail

Effect of heating rate on the pyrolysis of camel manure

Prakash Parthasarathy, Tareq Al‐Ansari, Hamish R. Mackey, Gordon McKay

2021Biomass Conversion and Biorefinery79 citationsDOIOpen Access PDF

Abstract

Abstract Information on the pyrolysis degradation kinetics of feedstock is critical for the design and fabrication of pyrolysis reactors. In this study, the pyrolytic behaviour of a novel biomass, camel manure, has been studied in a non-isothermal thermogravimetric analyser. The thermal analyses were performed from room temperature to 950 °C at different heating rates (10, 20, and 50°C/min) in an N 2 environment (100 ml/min). The kinetic parameters of the manure components are determined using an Arrhenius model equation, and the influence of heating rate on the pyrolytic characteristics and kinetic parameters of the manure components has been examined. The results indicated that the increase in heating rates increased the starting and ending temperatures (decomposition) of manure components. The increase in heating rates shifted the ignition, peak, and burnout temperatures to higher temperatures. At the same time, the increase in heating rates improved the char yield from 22.50 to 31.51%. However, the increase in heating rates showed an insignificant effect on the kinetic parameters of the camel manure components.

Topics & Concepts

PyrolysisCharArrhenius equationThermogravimetric analysisIsothermal processPyrolytic carbonManureChemistryRaw materialMaterials scienceThermal decompositionAnalyserDecompositionAnalytical Chemistry (journal)Chemical engineeringThermodynamicsActivation energyEnvironmental chemistryOrganic chemistryChromatographyAgronomyBiologyEngineeringPhysicsThermochemical Biomass Conversion ProcessesThermal and Kinetic AnalysisCoal Combustion and Slurry Processing