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A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity

Mayukh Bhadra, Wesley J. Transue, Hyeongtaek Lim, Ryan E. Cowley, Jung Yoon C. Lee, Maxime A. Siegler, Patrick Josephs, Gerald Henkel, Markus M. Lerch, Siegfried Schindler, Adam Neuba, Keith O. Hodgson, Britt Hedman, Edward I. Solomon, Kenneth D. Karlin

2021Journal of the American Chemical Society41 citationsDOIOpen Access PDF

Abstract

), are presented.

Topics & Concepts

ChemistryThioetherReactivity (psychology)SuperoxideStereochemistryPhotochemistryHydrogen atom abstractionResonance Raman spectroscopyExtended X-ray absorption fine structureRedoxCopperAbsorption spectroscopyRaman spectroscopyInorganic chemistryEnzymeHydrogenOrganic chemistryQuantum mechanicsAlternative medicineOpticsPhysicsMedicinePathologyMetal-Catalyzed Oxygenation MechanismsCO2 Reduction Techniques and CatalystsMetal complexes synthesis and properties
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