Enhanced Photocatalytic Performance of Visible-Light-Driven BiVO4 Nanoparticles through W and Mo Substituting
Chien‐Yie Tsay, Ching-Yu Chung, Chin‐Yi Chen, Yu‐Cheng Chang, Chi‐Jung Chang, Jerry J. Wu
Abstract
Bismuth vanadate (BiVO4), W-doped BiVO4 (BiVO4:W), and Mo-doped BiVO4 (BiVO4:Mo) nanoparticles were synthesized at pH = 4 using a green hydrothermal method. The effects of 2 at% W or Mo doping on the microstructural and optical characteristics of as-prepared BiVO4 nanoparticles and the effect of combining particle morphology modification and impurity dopant incorporation on the visible-light-derived photocatalytic degradation of dilute Rhodamine B (RhB) solution are studied. XRD examination revealed that these obtained BiVO4-based nanoparticles had a highly crystalline and single monoclinic phase. SEM and TEM observations showed that impurity doping could modify the surface morphology, change the particle shape, and reduce the particle diameter to enlarge their specific surface area, increasing the reactive sites of the photocatalytic process. XPS and FL measurements indicated that W- and Mo-doped nanoparticles possessed higher concentrations of oxygen vacancies, which could promote the n-type semiconductor property. It was found that the BiVO4:W and BiVO4:Mo powder samples exhibited better photocatalytic activity for efficient RhB removal than that shown by pristine BiVO4 powder samples under visible light illumination. That feature can be ascribed to the larger surface area and improved concentration of photogenerated charge carriers of the former.