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Modulating magnetic anisotropy in Ln( <scp>iii</scp> ) single-ion magnets using an external electric field

Arup Sarkar, Gopalan Rajaraman

2020Chemical Science30 citationsDOIOpen Access PDF

Abstract

Using a combination of theoretical tools, we show that the application of an external electric field in a certain direction can boost the axiality beyond that set by the ligands, opening up a new avenue for the generation of novel SIMs.

Topics & Concepts

Electric fieldMagnetAnisotropyMagnetic fieldField (mathematics)IonCondensed matter physicsMagnetic anisotropyPhysicsMaterials scienceEngineering physicsMagnetizationQuantum mechanicsMathematicsPure mathematicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications
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