Interfacial synthesis of crystalline two-dimensional cyano-graphdiyne
Zhaohui Zhang, Chenyu Wu, Qingyan Pan, Feng Shao, Qingzhu Sun, Siqi Chen, Zhibo Li, Yingjie Zhao
Abstract
A well-defined crystalline cyano-functionalized graphdiyne (CN-GDY) is synthesized at a liquid/liquid interface through alkyne-alkyne coupling reactions. The configurations and nanostructures of CN-GDY were well characterized by TEM, SEM, AFM, XPS, and Raman spectroscopy. HR-TEM and selected area electron diffraction (SAED) in combination with structure simulation firmly revealed a 9-fold stacking mode for CN-GDY.
Topics & Concepts
AlkyneX-ray photoelectron spectroscopyRaman spectroscopySelected area diffractionStackingMaterials scienceCrystallographyTransmission electron microscopyDiffractionElectron diffractionNanostructureChemical engineeringNanotechnologyChemistryOrganic chemistryCatalysisOpticsEngineeringPhysicsQuantum Dots Synthesis And PropertiesNanomaterials for catalytic reactionsSurface Chemistry and Catalysis