Biexcitons are bound in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>CsPbBr</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:math> perovskite nanocrystals
Yoonjae Park, David T. Limmer
Abstract
We study the energetics of quasiparticle excitations in ${\mathrm{CsPbBr}}_{3}$ perovskite nanocrystals using path integral molecular dynamics simulations. Employing detailed molecular models, we elucidate the interplay of anharmonic lattice degrees of freedom, dielectric confinement, and electronic correlation on exciton and biexciton binding energies of a range of nanocrystal sizes. We find generally good agreement with some experimental observations of binding energies and additionally explain the observed size-dependent Stokes shift. The explicit model calculations are compared with simplified approximations to rationalize the lattice contributions to binding. We find that polaron formation significantly reduces exciton binding energies, whereas these effects are negligible for biexciton interactions. While experimentally the binding energy of biexcitons is uncertain, based on our study, we conclude that biexcitons are bound in ${\mathrm{CsPbBr}}_{3}$.