Partially exposed RuP <sub>2</sub> surface in hybrid structure endows its bifunctionality for hydrazine oxidation and hydrogen evolution catalysis
Yapeng Li, Jihua Zhang, Yi Liu, Qizhu Qian, Ziyun Li, Yin Zhu, Genqiang Zhang
Abstract
at 1.0 V. The DFT calculations unravel the notability of partial exposure in the hybrid structure, as the exposed Ru atoms are the active sites for hydrazine dehydrogenation, while the C atoms exhibit a more thermoneutral value for H* adsorption.
Topics & Concepts
OverpotentialBifunctionalHydrazine (antidepressant)CatalysisElectrolysisDehydrogenationAnodeMaterials scienceBifunctional catalystHydrogen productionHydrogenDisproportionationChemical engineeringInorganic chemistryChemistryElectrodeElectrochemistryOrganic chemistryPhysical chemistryElectrolyteEngineeringChromatographyElectrocatalysts for Energy ConversionAdvanced battery technologies researchFuel Cells and Related Materials