Oxalato bridged coordination polymer of manganese(<scp>iii</scp>) involving unconventional O⋯π-hole(nitrile) and antiparallel nitrile⋯nitrile contacts: antiproliferative evaluation and theoretical studies
Debajit Dutta, Pranay Sharma, Antonio Frontera, Anshuman Gogoi, Akalesh K. Verma, Diksha Dutta, Bipul Sarma, Manjit K. Bhattacharyya
Abstract
Unconventional O⋯π-hole(nitrile) and antiparallel nitrile⋯nitrile contacts have been theoretically investigated for a Mn(<sc>iii</sc>) coordination polymer considering cytotoxicity, apoptosis, ROS generation, molecular docking and pharmacophore features.
Topics & Concepts
NitrileChemistryAntiparallel (mathematics)PharmacophoreMonomerPolymerStereochemistryCrystallographyOrganic chemistryPhysicsQuantum mechanicsMagnetic fieldMetal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes