Litcius/Paper detail

The mechanism of the molecular CISS effect in chiral nano-junctions

Thi Ngoc Ha Nguyen, Georgeta Salvan, Olav Hellwig, Yossi Paltiel, Lech Thomasz Baczewski, Christoph Tegenkamp

2024Chemical Science17 citationsDOIOpen Access PDF

Abstract

-curves. This is the first time that the CISS effect is demonstrated for a tunneling junction without a direct interface between the helical molecules and the magnetic substrate. Our results can be explained by a spin-polarized or spin-selective interface effect, induced and defined by the helicity and electric dipole orientation of the molecule at the interface. In this sense, the helical molecule does not act as a simple spin-filter or spin-polarizer and the CISS effect is not limited to spinterfaces.

Topics & Concepts

Substrate (aquarium)MoleculeNano-Mechanism (biology)NanotechnologyChemical physicsAdsorptionMaterials scienceChemistryCrystallographyPhysicsPhysical chemistryQuantum mechanicsComposite materialOrganic chemistryOceanographyGeologyMolecular Junctions and NanostructuresSurface Chemistry and CatalysisQuantum and electron transport phenomena