Expanding the horizons of porphyrin metal–organic frameworks <i>via</i> catecholate coordination: exploring structural diversity, material stability and redox properties
Siddhartha De, Georges Mouchaham, Fangbing Liu, Maame Affram, Brian Abeykoon, Nathalie Guillou, Erwann Jeanneau, Jean−Marc Grenèche, Lhoussain Khrouz, Charlotte Martineau, Lotfi Boudjema, Fabrice Salles, Pablo Salcedo‐Abraira, Gonçalo Valente, Manuel Souto, Alexandra Fateeva, Thomas Devic
Abstract
/Li), confirming the interest of redox active phenolate ligands for applications involving electron transfer. Our findings expand the library of porphyrin-based MOFs and highlight the potential of phenolate ligands for advancing the field of MOFs for energy storage materials.
Topics & Concepts
PorphyrinMetal-organic frameworkRedoxSBusMesoporous materialElectrochemistryLigand (biochemistry)AdsorptionElectron transferReactivity (psychology)ChemistryMaterials scienceCombinatorial chemistryInorganic chemistryPhotochemistryElectrodePhysical chemistryOrganic chemistryCatalysisReceptorMedicineAlternative medicinePathologyBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesMachine Learning in Materials Science