Litcius/Paper detail

Metal-free synthesis of secondary amides using <i>N</i>-Boc-<i>O</i>-tosylhydroxylamine as nitrogen source <i>via</i> Beckmann rearrangement

Jawahar L. Jat, Puneet Kumar, Saumya Verma, Dinesh Chandra, Vikram Singh, Bhoopendra Tiwari

2022New Journal of Chemistry14 citationsDOI

Abstract

An efficient methodology for the direct synthesis of secondary amides from ketones has been developed by using N -Boc- O -tosylhydroxylamine (TsONHBoc).

Topics & Concepts

ChemistryBeckmann rearrangementNitrogenMetalOrganic chemistryCombinatorial chemistryMedicinal chemistryOximeAsymmetric Hydrogenation and CatalysisAdvanced Synthetic Organic ChemistryChemical Synthesis and Analysis