Synthesis and electrochemical properties of nanocubes Mn2SnS3 for high-performance supercapacitors
Mona Sanayee, Majid Arvand
Abstract
Abstract Exploring environment-friendly active material-electrolyte combinations has become increasingly necessary with the rising use of supercapacitors. In this study, the potential of ternary Mn 2 SnS 3 on Ni foam as an electrode material was considered. The study investigated the impact of precursors on the morphology of the prepared electrodes utilizing techniques such as X-ray diffraction, energy dispersive X-ray analysis, field-emission scanning electron microscopy, and transmission electron microscopy. Nanocubes Mn 2 SnS 3 (NC-MTS) and nanoworms Mn 2 SnS 3 (NW-MTS) were synthesized via a facile solvothermal route. The results suggest that NC-MTS exhibits better capacitive performance compared with NW-MTS, which means that morphology has a significant effect on the electrochemical reaction. NC-MTS presents excellent supercapacitor performances with a high specific capacity of about 2115 F g −1 at current density 2 A g −1 , excellent rate capability of 78% at 17 A g −1 and excellent cycling stability 92% capacitance retention after 3000 GCD cycles. Whereas, NW-MTS illustrated a specific capacity of about 853 F g −1 at current density 2 A g −1 , rate capability of 50% at 17 A g −1 and cycling stability of 81% capacitance retention after 3000 GCD cycles. Additionally, an asymmetric supercapacitor NC-MTS/NF//AC based on the NC-MTS/NF as a positive electrode and activated carbon (AC) as a negative electrode was successfully constructed with the excellent electrochemical performance, which demonstrated a high energy density of 60.56 Wh kg −1 and a high power density of 699.89 W kg −1 .