g‐C<sub>3</sub>N<sub>4</sub> Photocatalyzed Decarboxylative Oxidation of Carboxylic Acids and the Oxidation of Alkenes and Alkanes
Sangita Bishi, Bhabani Sankar Lenka, Peter Kreitmeier, Oliver Reiser, Debayan Sarkar
Abstract
Abstract The decarboxylative oxygenation of readily available carboxylic acids as well as the oxidation of alkenes and alkanes has been accomplished through visible light using g‐C 3 N 4 as a robust and recyclable catalyst. The scalable protocol furnishes an array of aldehydes and ketones under mild reaction conditions, requiring only molecular oxygen as an oxidant. Notably, no addition of stochiometric amounts of base is required, and furthermore, the reaction proceeds efficiently open to the air.
Topics & Concepts
ChemistryDecarboxylationOrganic chemistryPhotocatalysisCarboxylic acidPhotochemistryCatalysisAdvanced Photocatalysis TechniquesAdvanced Nanomaterials in CatalysisChemical Synthesis and Reactions