Visible light-mediated NHC and photoredox co-catalyzed 1,2-sulfonylacylation of allenes<i>via</i>acyl and allyl radical cross-coupling
Lihong V. Wang, Jiaqiong Sun, Jiuli Xia, Ruiyang Ma, Guangfan Zheng, Qian Zhang
Abstract
Visible light-mediated NHC and photoredox co-catalyzed radical 1,2-sulfonylacylation of allenes via cross-coupling between an allyl radical and an NHC-stabilized acyl radical.
Topics & Concepts
ChemistryCatalysisPhotochemistryCoupling (piping)Visible spectrumPhotoredox catalysisOrganic chemistryPhotocatalysisMechanical engineeringPhysicsEngineeringOptoelectronicsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsRadical Photochemical Reactions