Litcius/Paper detail

Determination of the Conversion and Efficiency for CO<sub>2</sub> in an Atmospheric Pressure Microwave Plasma Torch

K. Wiegers, Andreas Schulz, M. Walker, Günter E. M. Tovar

2022Chemie Ingenieur Technik25 citationsDOIOpen Access PDF

Abstract

Abstract In a 2.45 GHz plasma torch, carbon dioxide (CO 2 ) has been converted into carbon monoxide (CO) and oxygen (O 2 ) at atmospheric pressure. The conversion and the efficiency of the plasma have been determined using two independent measuring methods: mass spectrometry and Fourier transform infrared absorption spectroscopy. The conversion depends on the measurement position in the exhaust gas duct. The conversion values at the beginning of the exhaust gas duct are significantly higher (maximum conversion is 22 %) than in the thermalized state at the end of the duct. In the cold, thermalized state of the gas, the maximum conversion rate is 8 % at 1.5 eV molecule −1 . The maximum efficiency of 25 % is achieved at approximatively 0.6 eV molecule −1 operating at a microwave power of 0.48 kW and a mass flow of 12 slm CO 2 .

Topics & Concepts

Analytical Chemistry (journal)Carbon monoxideAtmospheric pressureEnergy conversion efficiencyChemistryMicrowavePlasmaVolumetric flow rateTorchPlasma torchMass spectrometryCarbon dioxideExhaust gasMaterials scienceCatalysisOptoelectronicsEnvironmental chemistryChromatographyMetallurgyPhysicsGeologyOceanographyBiochemistryQuantum mechanicsWeldingOrganic chemistryPlasma Applications and DiagnosticsPlasma Diagnostics and ApplicationsCatalytic Processes in Materials Science