A Systematic Study of the Temperature-Induced Performance Decline of <i>ansa</i>-Metallocenes for iPP
Christian Ehm, Antonio Vittoria, Georgy P. Goryunov, Vyatcheslav V. Izmer, Dmitry S. Kononovich, Pavel S. Kulyabin, Rocco Di Girolamo, Peter H. M. Budzelaar, Alexander Z. Voskoboynikov, Vincenzo Busico, Dmitry V. Uborsky, Roberta Cipullo
Abstract
Highly accurate high-throughput experimentation (HTE) data for a set of 21 silicon-bridged C2-symmetric ansa-zirconocenes in propene homopolymerization were collected and were used to develop quant...
Topics & Concepts
StereoselectivityRegioselectivityChemistrySteric effectsMonomerPolymerizationPropeneSiliconCatalysisPolymer chemistryComputational chemistryPolymerStereochemistryOrganic chemistryOrganometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysisSynthetic Organic Chemistry Methods