Stepwise assembly and reversible structural transformation of ligated titanium coated bismuth-oxo cores: shell morphology engineering for enhanced chemical fixation of CO<sub>2</sub>
Qing-Rong Ding, Yinghua Yu, Changsheng Cao, Jian Zhang, Lei Zhang
Abstract
cycloaddition with epoxides under ambient conditions, whose activity was significantly influenced by the outer ligated titanium shell structure. This work provides a new insight into the construction of atomically precise heterometallic core-shell nanostructures and also an interesting shell engineering strategy for tuning their physicochemical properties.
Topics & Concepts
Materials scienceTitaniumPhotocatalysisOxideShell (structure)NanotechnologyCluster (spacecraft)NanostructureBismuthChemical engineeringSteric effectsCatalysisChemistryStereochemistryComposite materialMetallurgyOrganic chemistryProgramming languageComputer scienceEngineeringAdvanced Photocatalysis TechniquesPolyoxometalates: Synthesis and ApplicationsCO2 Reduction Techniques and Catalysts