Mechanistic investigation of a visible light mediated dehalogenation/cyclisation reaction using iron(<scp>iii</scp>), iridium(<scp>iii</scp>) and ruthenium(<scp>ii</scp>) photosensitizers
Akin Aydogan, Rachel E. Bangle, Simon De Kreijger, John C. Dickenson, Michael L. Singleton, Émilie Cauët, Alejandro Cadranel, Gerald J. Meyer, Benjamin Elias, Renato N. Sampaio, Ludovic Troian‐Gautier
Abstract
The identification of reaction mechanisms unique to the iron, ruthenium, and iridium PS represents progress towards the long-sought goal of utilizing earth-abundant, first-row transition metals for emerging energy and environmental applications.
Topics & Concepts
IridiumRutheniumHalogenationChemistryCatalysisCombinatorial chemistryPhotochemistryOrganic chemistryRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsNanocluster Synthesis and Applications