Transborylation of alkenylboranes with diboranes
Paula Dominguez‐Molano, Gerard Bru, Oriol Salvadó, Ricardo J. Maza, Jorge J. Carbó, Elena Fernández
Abstract
Exchange of boryl moieties is possible between alkenylboranes and diboron reagents as a stereospecific cross-metathesis with formation of mixed diboron reagents. DFT calculations propose a mechanism with both symmetric and non-symmetric diboron reagents.
Topics & Concepts
ReagentStereospecificityChemistryMetathesisSalt metathesis reactionCombinatorial chemistryStereochemistryOrganic chemistryCatalysisPolymerizationPolymerOrganoboron and organosilicon chemistrySynthetic Organic Chemistry MethodsChemical Synthesis and Analysis