Electrochemical N-Acylation of Sulfoximine with Hydroxamic Acid
Wenxiu Huang, Shoucai Wang, Mingzhe Li, Longqiang Zhao, Mengyu Peng, Chen Kang, Guangbin Jiang, Fanghua Ji
Abstract
Despite the widespread applications of sulfoximines, green and efficient access to functionalized sulfoximines remains a challenge. By employing an electrochemical strategy, we describe an approach for the construction of N -aroylsulfoximines, which features a broad substrate scope, mild reaction conditions, safety on a gram scale, and no need for an external oxidant and transition metal catalysts.
Topics & Concepts
ElectrochemistryScope (computer science)Hydroxamic acidAcylationSubstrate (aquarium)Combinatorial chemistryCatalysisChemistryComputer scienceOrganic chemistryElectrodeGeologyOceanographyProgramming languagePhysical chemistrySynthesis and Catalytic ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques