CF<sub>3</sub>-substituted sulfonium cations as efficient chalcogen bond donors towards cyanometalates
Tim‐Niclas Streit, Rosa M. Gomila, Robin Sievers, Antonio Frontera, Moritz Malischewski
Abstract
Fine-tuning of the electrostatic potentials of sulfonium cations influences the lengths of S⋯N chalcogen bonds in supramolecular assemblies.
Topics & Concepts
ChalcogenSulfoniumSupramolecular chemistryChemistryArylCrystallographyGroup (periodic table)Crystal structureStereochemistryOrganic chemistrySalt (chemistry)AlkylFluorine in Organic ChemistrySulfur-Based Synthesis TechniquesSynthesis and Catalytic Reactions