A multi-faceted approach to probe organic phase composition in TODGA systems with 1-alcohol phase modifiers
Allison A. Peroutka, Shane S. Galley, Jenifer C. Shafer
Abstract
. Increasing the 1-alcohol concentration to 30 vol% results in the opposite trend, with longer alkyl chains suppressing aggregation. These results suggest this approach is effective at probing trends in the organic phase micro-structure, and indicates trends across the Ln period with various 1-alcohol alkyl chain lengths are a function of outer-sphere coordination.
Topics & Concepts
AlkylAlcoholChemistryExtraction (chemistry)Phase (matter)HexanolOctanolSolventHydrogen bondOrganic chemistryMoleculePartition coefficientRadioactive element chemistry and processingExtraction and Separation ProcessesChemical and Physical Properties in Aqueous Solutions