A large dinuclear Fe(<scp>ii</scp>) triple helicate demonstrating a two-step spin crossover
Kyle J. Howard-Smith, Alexander R. Craze, Hikaru Zenno, Junya Yagyu, Shinya Hayami, Feng Li
Abstract
Reported herein, the synthesis as well as the structural and magnetic characterisation of the largest reported dinuclear Fe(ii) triple helicate system to exhibit spin crossover-and also a rare example of a 273° helical twist using aromatic spacers-is presented, with exploration of the two-step spin-transition observed.
Topics & Concepts
Spin crossoverCrossoverChemistryNanotechnologyMaterials scienceCrystallographyComputer scienceArtificial intelligenceMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies