The different magnetic relaxation behaviors in [Fe(CN)<sub>6</sub>]<sup>3−</sup> or [Co(CN)<sub>6</sub>]<sup>3−</sup> bridged 3d–4f heterometallic compounds
Ruirui Wang, Haili Wang, Juan Wang, Feifei Bai, Yue Ma, Licun Li, Qing‐Lun Wang, Bin Zhao, Peng Cheng
Abstract
For the isomorphic tetranuclear 3d–4f compounds constructed by [M(CN)<sub>6</sub>]<sup>3−</sup> linking Ln<sup>III</sup>-Schiff-base units, the diamagnetic Co<sup>III</sup> ions in the system could suppress QTM effectively and obtain a field-induced SMMs behavior.
Topics & Concepts
DiamagnetismIonCrystallographyMagnetic relaxationChemistryRelaxation (psychology)MagnetismMaterials scienceAnalytical Chemistry (journal)Atomic physicsMagnetizationMagnetic fieldPhysicsCondensed matter physicsOrganic chemistryChromatographySocial psychologyPsychologyQuantum mechanicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research