A CO<sub>2</sub>-mediated base catalysis approach for the hydration of triple bonds in ionic liquids
Minhao Tang, Fengtao Zhang, Yanfei Zhao, Yuepeng Wang, Zhengang Ke, Ruipeng Li, Wei Zeng, Buxing Han, Zhimin Liu
Abstract
CO 2 mediates ILs to serve as base catalysts for the activation of triple bonds, which achieves hydration of nitriles and CC containing compounds to carbonyl compounds under metal-free conditions.
Topics & Concepts
Ionic liquidCatalysisTriple bondChemistryBase (topology)Ionic bondingBase metalMetalMetal carbonylCombinatorial chemistryOrganic chemistryDouble bondMaterials scienceIonMathematicsMathematical analysisWeldingMetallurgyIonic liquids properties and applicationsAsymmetric Hydrogenation and CatalysisChemical Synthesis and Reactions