Design and Formulation of Engineered 2D Nb<sub><b>2</b></sub>CT<sub><b><i>x</i></b></sub> MXene for Ultra-Stable NH<sub><b>4</b></sub><sup><b>+</b></sup> Aqueous Hybrid Supercapacitors
Hongjia Ren, Muhammad Sufyan Javed, Salamat Ali, Xinze Zhang, Awais Ahmad, Iftikhar Hussain, Munirah D. Albaqami, Xin Wang, Weihua Han
Abstract
Two-dimensional (2D) transition metal carbides/nitrides (MXenes), which possess layered structures with excellent electrical conductivity, are auspicious materials for energy storage applications. The presence of van der Waals interactions between Nb 2 CT x MXene nanosheets tends to induce self-stacking, which reduces the accessible surface area and the number of electrochemically active sites. This structural limitation adversely affects cycling stability and specific capacitance when employed in supercapacitor applications. Herein, nitrogen (N)-functionalized Nb 2 CT x MXene (N-Nb 2 CT x ) materials were optimized by annealing Nb 2 CT x in an ammonia (NH 3 ) atmosphere at different temperatures (denoted as N-Nb 2 CT x -300 °C, N-Nb 2 CT x -400 °C, and N-Nb 2 CT x -500 °C). Based on the experimental results in the three-electrode system, it was found that N-Nb 2 CT x -400 °C exhibited the most favorable electrochemical performance, attributed to effective nitrogen doping and enhanced structural stability. Annealing at 400 °C helps nitrogen atoms to be more evenly doped into the lattice of Nb 2 CT x, thereby increasing the material’s surface area and porosity while minimizing significant structural agglomeration and partial decomposition or oxidation. N-Nb 2 CT x -400 °C shows a specific capacitance of 382 F/g at 1 A/g, retaining 140 F/g at a current density of 20 A/g in ammonium sulfate ((NH 4 ) 2 SO 4 ) electrolyte. Assembled NH 4 + ion hybrid supercapacitors (AHSCs) exhibit a specific energy density of 23.36 Wh/kg at a power density of 900 W/kg. Through density functional theory (DFT) calculations, it is revealed that N-Nb 2 CT x MXene exhibits superior thermodynamic and diffusion properties toward SO 4 2– and NH 4 + ions, providing theoretical guidance for the design and development of high-performance electrode materials for energy storage devices.